chem-dft-orca-optimization

chem-dft-orca-optimization is a skill for Claude Code, Codex from learningmatter-mit/AtomisticSkills. It costs 37 tokens per session (2,004 once invoked), scanned A, original, MIT.

A quantum-chemistry workflow that uses ORCA to adjust a molecule’s atomic positions. It can seek either a nearby low-energy structure or a transition state, the high-energy point between reactants and products.

In plain words
What is it for?
Optimizing molecular structures with density functional theory, either by finding stable geometries or searching for a single transition-state structure.
Why use it?
It removes the need to manage the geometry-optimization process and convergence settings manually.

Skill for Claude CodeCodex

Install

Getting it into your agent

One page per mod, every tool's command on it. A separate URL per tool would split the same page into five that compete with each other.

agentmods
npx agentmods add skills/learningmatter-mit/atomisticskills/chem-dft-orca-optimization
Any agent
npx skills add learningmatter-mit/AtomisticSkills --skill chem-dft-orca-optimization
Clone the repo
git clone --depth 1 https://github.com/learningmatter-mit/AtomisticSkills

Made for: Claude Code, Codex.

Wrote this? Show the measurements

A badge with what this costs and how it scanned, read live from this page, so it follows the numbers instead of freezing them. Markdown for a README, HTML for a documentation site or a project page.

agentmods badge for chem-dft-orca-optimization

README.md
[![agentmods](https://agentmods.dev/badge/skills/learningmatter-mit/atomisticskills/chem-dft-orca-optimization.svg)](https://agentmods.dev/skills/learningmatter-mit/atomisticskills/chem-dft-orca-optimization)
Your own site
<a href="https://agentmods.dev/skills/learningmatter-mit/atomisticskills/chem-dft-orca-optimization"><img src="https://agentmods.dev/badge/skills/learningmatter-mit/atomisticskills/chem-dft-orca-optimization.svg" alt="Measured on agentmods" height="20"></a>
Per session 37 Skills are progressive disclosure: only the name and description are preloaded; the body loads when the skill is used.
When invoked 2,004 The whole file, excluding the scripts and references it only reads on demand.
Security scan A 0 findings. Scan, not verified.
Origin original No closer match found in the catalogue.
Token cost

What it costs to keep this loaded

Counted locally with the o200k_base tokenizer, which is exact for GPT models; Claude uses its own tokenizer and its counts differ. Treat this as one consistent yardstick across the catalogue rather than a bill. Prices are per million input tokens.

ModelPer sessionOnce invoked
Fable 5 $0.00037 $0.02004
Opus 5 $0.00018 $0.01002
Sonnet 5 $0.00007 $0.00401
Haiku 4.5 $0.00004 $0.00200

Measured 4d ago against content hash 5bd0357f1b23, method: parsed. Prices are Anthropic first-party input rates as of 2026-08-30, from the pricing page.

Security

Grade A, and why

chem-dft-orca-optimization scanned grade A with 0 findings against 26 rules in 11 categories — prompt injection, anti-refusal, data exfiltration, privilege escalation, supply chain, agent snooping, system-prompt leakage, SSRF and excessive agency — measured 4d ago.

The scan reads SKILL.md. This mod also ships 1 executable file (scripts/run_optimization.py), listed below but not scanned — reading those needs a real analyzer, not pattern matching.

A static scan of the body, not an audit. Every finding is printed with the line that produced it so you can judge whether it matters here. A mod is markdown that instructs an agent; that is exactly why what it instructs is worth reading.

Nothing flagged

None of the 26 patterns this scan looks for appear in this file: no shell pipes, no recursive deletes, no credential paths, no hidden text, no instruction-override or anti-refusal phrasing, no agent-config snooping. That is not a guarantee, it is the absence of the things that are checkable.

.agents/skills/chem-dft-orca-optimization/SKILL.md · 157 lines

How it starts

The opening of the file, as written. The whole thing — 157 lines — stays where its author put it; the contents beside it link to each section on GitHub.

DFT Geometry Optimization with ORCA

Goal

Optimize the geometry of a molecular structure at the DFT level using the ORCA quantum chemistry program. Supports two modes: minimization (finding the nearest local minimum) and transition state (TS) optimization (single-ended saddle point search). The calculation uses the SCINE/ReaDuct wrapper for robust optimizer management.

[!IMPORTANT] This skill provides single-ended TS optimization only. For reaction pathway methods (NEB, IRC), consider using the MLIP-based NEB skill or IRC skill with MLIP pre-screening, then refine with DFT. For advanced ORCA features, use the advanced ORCA skill.

Background

Geometry optimization iteratively adjusts nuclear positions to minimize (or, for TS search, to find a first-order saddle point of) the potential energy surface $E(\mathbf{R})$. The SCINE/ReaDuct optimizer handles step control, coordinate transformations, and convergence criteria internally.

  • Minimization seeks a stationary point where $\nabla E = 0$ and the Hessian has all positive eigenvalues.
  • TS optimization seeks a first-order saddle point where $\nabla E = 0$ and the Hessian has exactly one negative eigenvalue.

1. Prerequisites

  • Conda environment: orca-agent with scine_utilities, scine_readuct, and ase installed
  • ORCA binary: The environment variable ORCA_BINARY_PATH must point to the ORCA executable
    export ORCA_BINARY_PATH=/path/to/orca
    
  • Input structure: A molecular structure file readable by ASE (.xyz, .cif, .mol, etc.)
  • For TS optimization: Provide a reasonable TS guess geometry. Poor initial guesses will likely fail to converge to the correct saddle point.

2. Parameters

Parameter Default Description
--structure (required) Path to input structure file
--opt_type min min for minimization, ts for transition state search
--charge 0 Molecular charge
--spin_multiplicity 1 Spin multiplicity (2S+1)
--functional PBE DFT functional (e.g. PBE, B3LYP, wB97X-V)
--basis_set def2-SVP Basis set (e.g. def2-SVP, def2-TZVP)
--dispersion None Dispersion correction (e.g. D3BJ, D4)
--solvation None Implicit solvation model: CPCM or SMD
--solvent None Solvent name; required if --solvation is set
--special_option NOSOSCF ORCA special option passed to SCINE calculator. Set to empty string to disable.
--nprocs 1 Number of CPU cores for ORCA
--convergence_max_iterations 200 Maximum optimization steps
--calculate_final_hessian off Compute Hessian at optimized geometry (for TS verification)
--calculator_settings None Extra SCINE calculator settings as a JSON string (see below)
--optimizer_settings None Extra ReaDuct optimizer kwargs as a JSON string (see below)
--output_dir auto Output directory

Read the full file on GitHub · 157 lines

Files

What ships with it

5 files beside SKILL.md in the same directory: the scripts, references and assets a skill reads on demand. Not counted in the per-session cost; read them before you install if any of them is executable.

Changes

What this file has done since we first saw it

Hashed on every crawl. A supply-chain change to an agent config is a question of when, not whether, so the history is kept rather than the latest state alone.

  1. 4d ago First seen · 157 lines · 37 tokens per session scan A 5bd0357f1b23

Subscribe to this mod's changes

chem-dft-orca-optimization is a skill published in the GitHub repository learningmatter-mit/AtomisticSkills (158 stars, last pushed yesterday), licensed MIT. It adds 37 tokens to every session and 2,004 once invoked, about $0.0002 per session on Opus 5. A static security scan graded it A with 0 findings. No closer match exists in the catalogue, so it is treated as the original; first seen 2026-08-30.

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